In mineralogy, diamond (from the ancient Greek αδάμας – adámas “unbreakable”) is an allotrope of carbon, where the carbon atoms are arranged in a variation of the face-centered cubic crystal structure called a diamond lattice. Diamond is less stable than graphite, but the conversion rate from diamond to graphite is negligible at ambient conditions. Diamond is renowned as a material with superlative physical qualities, most of which originate from the strong covalent bonding between its atoms. In particular, diamond has the highest hardness and thermal conductivity of any bulk material. Those properties determine the major industrial application of diamond in cutting and polishing tools.
Diamond has remarkable optical characteristics. Because of its extremely rigid lattice, it can be contaminated by very few types of impurities, such as boron and nitrogen. Combined with wide transparency, this results in the clear, colorless appearance of most natural diamonds. Small amounts of defects or impurities (about one per million of lattice atoms) color diamond blue (boron), yellow (nitrogen), brown (lattice defects), green (radiation exposure), purple, pink, orange or red. Diamond also has relatively high optical dispersion (ability to disperse light of different colors), which results in its characteristic luster. Excellent optical and mechanical properties, combined with efficient marketing, make diamond the most popular gemstone.
Most natural diamonds are formed at high-pressure high-temperature conditions existing at depths of 140 to 190 kilometers (87 to 120 mi) in the Earth mantle. Carbon-containing minerals provide the carbon source, and the growth occurs over periods from 1 billion to 3.3 billion years (25% to 75% of the age of the Earth). Diamonds are brought close to the Earth surface through deep volcanic eruptions by a magma, which cools into igneous rocks known as kimberlites and lamproites. Diamonds can also be produced synthetically in a high-pressure high-temperature process which approximately simulates the conditions in the Earth mantle. An alternative, and completely different growth technique is chemical vapor deposition (CVD). Several non-diamond materials, which include cubic zirconia and silicon carbide and are often called diamond simulants, resemble diamond in appearance and many properties. Special gemological techniques have been developed to distinguish natural and synthetic diamonds and diamond simulants.
The name diamond is derived from the ancient Greek αδάμας (adámas), “proper”, “unalterable”, “unbreakable”, “untamed”, from ἀ- (a-), “un-” + δαμάω (damáō), “I overpower”, “I tame”.[3] Diamonds are thought to have been first recognized and mined in India, where significant alluvial deposits of the stone could be found many centuries ago along the rivers Penner, Krishna and Godavari. Diamonds have been known in India for at least 3,000 years but most likely 6,000 years.
Diamonds have been treasured as gemstones since their use as religious icons in ancient India. Their usage in engraving tools also dates to early human history.[5][6] The popularity of diamonds has risen since the 19th century because of increased supply, improved cutting and polishing techniques, growth in the world economy, and innovative and successful advertising campaigns.
In 1772, Antoine Lavoisier used a lens to concentrate the rays of the sun on a diamond in an atmosphere of oxygen, and showed that the only product of the combustion was carbon dioxide, proving that diamond is composed of carbon. Later in 1797, Smithson Tennant repeated and expanded that experiment. By demonstrating that burning diamond and graphite releases the same amount of gas he established the chemical equivalence of these substances.
The most familiar use of diamonds today is as gemstones used for adornment, a use which dates back into antiquity. The dispersion of white light into spectral colors is the primary gemological characteristic of gem diamonds. In the 20th century, experts in gemology have developed methods of grading diamonds and other gemstones based on the characteristics most important to their value as a gem. Four characteristics, known informally as the four Cs, are now commonly used as the basic descriptors of diamonds: these are carat, cut, color, and clarity.[9] A large, flawless diamond is known as a paragon.
A diamond is a transparent crystal of tetrahedrally bonded carbon atoms (sp3) that crystallizes into the diamond lattice which is a variation of the face centered cubic structure. Diamonds have been adapted for many uses because of the material’s exceptional physical characteristics. Most notable are its extreme hardness and thermal conductivity (900–2,320 W·m−1·K−1),[10] as well as wide bandgap and high optical dispersion.[11] Above 1,700 °C (1,973 K / 3,583 °F) in vacuum or oxygen-free atmosphere, diamond converts to graphite; in air, transformation starts at ~700 °C.[12] Diamond’s ignition point is 720 – 800 °C in oxygen and 850 – 1,000 °C in air.[13] Naturally occurring diamonds have a density ranging from 3.15–3.53 g/cm3, with pure diamond close to 3.52 g/cm3.[1] The chemical bonds that hold the carbon atoms in diamonds together are weaker than those in graphite. In diamonds, the bonds form an inflexible three-dimensional lattice, whereas in graphite, the atoms are tightly bonded into sheets, which can slide easily over one another, making the overall structure weaker.
Hardness
Hardness
Diamond is the hardest known natural material on the Mohs scale of mineral hardness, where hardness is defined as resistance to scratching and is graded between 1 (softest) and 10 (hardest). Diamond has a hardness of 10 (hardest) on this scale.[15] Diamond’s hardness has been known since antiquity, and is the source of its name.
Diamond hardness depends on its purity, crystalline perfection and orientation: hardness is higher for flawless, pure crystals oriented to the <111> direction (along the longest diagonal of the cubic diamond lattice).[16] Therefore, whereas it might be possible to scratch some diamonds with other materials, such as boron nitride, the hardest diamonds can only be scratched by other diamonds and nanocrystalline diamond aggregates.
The hardness of diamond contributes to its suitability as a gemstone. Because it can only be scratched by other diamonds, it maintains its polish extremely well. Unlike many other gems, it is well-suited to daily wear because of its resistance to scratching—perhaps contributing to its popularity as the preferred gem in engagement or wedding rings, which are often worn every day.
The hardest natural diamonds mostly originate from the Copeton and Bingara fields located in the New England area in New South Wales, Australia. These diamonds are generally small, perfect to semiperfect octahedra, and are used to polish other diamonds. Their hardness is associated with the crystal growth form, which is single-stage crystal growth. Most other diamonds show more evidence of multiple growth stages, which produce inclusions, flaws, and defect planes in the crystal lattice, all of which affect their hardness. It is possible to treat regular diamonds under a combination of high pressure and high temperature to produce diamonds that are harder than the diamonds used in hardness gauges.
Somewhat related to hardness is another mechanical property toughness, which is a material’s ability to resist breakage from forceful impact. The toughness of natural diamond has been measured as 7.5–10 MPa·m1/2.[18][19] This value is good compared to other gemstones, but poor compared to most engineering materials. As with any material, the macroscopic geometry of a diamond contributes to its resistance to breakage. Diamond has a cleavage plane and is therefore more fragile in some orientations than others. Diamond cutters use this attribute to cleave some stones, prior to faceting.[20] “Impact toughness” is one of the main indexes to measure the quality of synthetic industrial diamonds.
Electrical conductivity
Other specialized applications also exist or are being developed, including use as semiconductors: some blue diamonds are natural semiconductors, in contrast to most diamonds, which are excellent electrical insulators. The conductivity and blue color originate from boron impurity. Boron substitutes for carbon atoms in the diamond lattice, donating a hole into the valence band.
Other specialized applications also exist or are being developed, including use as semiconductors: some blue diamonds are natural semiconductors, in contrast to most diamonds, which are excellent electrical insulators. The conductivity and blue color originate from boron impurity. Boron substitutes for carbon atoms in the diamond lattice, donating a hole into the valence band.
Substantial conductivity is commonly observed in nominally undoped diamond grown by chemical vapor deposition. This conductivity is associated with hydrogen-related species adsorbed at the surface, and it can be removed by annealing or other surface treatments.
Surface property
Diamonds are lipophilic and hydrophobic, which means the diamonds’ surface cannot be wet by water but can be easily wet and stuck by oil. This property can be utilized to extract diamonds using oil when making synthetic diamonds.
Chemical stability
Diamonds are lipophilic and hydrophobic, which means the diamonds’ surface cannot be wet by water but can be easily wet and stuck by oil. This property can be utilized to extract diamonds using oil when making synthetic diamonds.
Chemical stability
Diamonds’ chemical property is very stable. Under room temperature diamonds do not react with any chemical reagents including various kinds of acid and alkali. Diamonds’ surface can only be oxidized a little by just a few oxidants under high temperature (below 1,000 °C). So acid and alkali can be used to refine synthetic diamond.
Here is an illustration of diamonds of different values. |  |  |  |
| Low ValueThis is a .32 carat, SI clarity, J color diamond. Such a diamond can be bought for a few hundred dollars. | HighValueThis is a 1.37 carat, VS clarity, F color diamond. You can buy a diamond like this for under $10,000. | Very High ValueHere is a 5 carat diamond with VVS clarity, and G color. This diamond can be found for sale at around $200,000. | Highest ValueHere is a fancy blue 45 carat diamond. It is so valuable, that it possibly priceless. It lives in the Smithsonian Museum and is called the Hope Daimond. |
| General | |
|---|---|
| Category | Native Minerals |
| Chemical formula | C |
| Strunz classification | 01.CB.10a |
| Identification | |
| Molar mass | 12.01 g·mol-1 |
| Color | Typically yellow, brown or gray to colorless. Less often blue, green, black, translucent white, pink, violet, orange, purple and red. |
| Crystal habit | Octahedral |
| Crystal system | Isometric-Hexoctahedral (Cubic) |
| Cleavage | 111 (perfect in four directions) |
| Fracture | Conchoidal (shell-like) |
| Mohs scale hardness | 10 |
| Luster | Adamantine |
| Streak | Colorless |
| Diaphaneity | Transparent to subtransparent to translucent |
| Specific gravity | 3.52±0.01 |
| Density | 3.5–3.53 g/cm3 |
| Polish luster | Adamantine |
| Optical properties | Isotropic |
| Refractive index | 2.418 (at 500 nm) |
| Birefringence | None |
| Pleochroism | None |
| Dispersion | 0.044 |
| Melting point | Pressure dependent |
